Beilstein J. Org. Chem.2018,14, 2956–2963, doi:10.3762/bjoc.14.275
turnover event of an olefin metathesis reaction using a new family of homogenous Ru-based catalysts bearing modified indenylideneligands has been investigated, using methoxyethylene as a substrate. The study is carried out by means of density functional theory (DFT). The indenylideneligands are decorated
that to describe the reactivity, structural, and electronic parameters must be taken into account. The indenylideneligands, especially the more sterically demanding, impose higher electrophilicity on the ruthenium centre, but structurally favour the relative stability of the metallacycle in order to
Beilstein J. Org. Chem.2010,6, 1167–1173, doi:10.3762/bjoc.6.133
the Ru(II)–Ru(III) mixed-valence compound [(p-cymene)Ru(μ-Cl)3RuCl2(PCy3)], which was found to be an efficient promoter for atom transfer radical reactions under the adopted experimental conditions.
Keywords: Grubbs catalyst; indenylideneligands; Kharasch reaction; microwave heating; olefin
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Graphical Abstract
Scheme 1:
Reaction of homobimetallic ruthenium–indenylidene complex 1 with ethylene.